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Effect of dilution rate on dynamic and steady-state biofilm characteristics during phenol biodegradation

Veena Bangalore Rangappa, Vidya Shetty Kodialbail, Saidutta Malur Bharthaiyengar

《环境科学与工程前沿（英文）》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0863-9

摘要： Continuous pulsed plate bioreactor (PPBR) was used for phenol biodegradation. cells immobilized on granular activated carbon was used. Dynamic and steady state biofilm characteristics depend on dilution rate (DR). Lower DR favour phenol degradation and uniform, thick biofilm formation. Exo polymeric substance production in biofilm are favoured at lower dilution rates. Pulsed plate bioreactor (PPBR) is a biofilm reactor which has been proven to be very efficient in phenol biodegradation. The present paper reports the studies on the effect of dilution rate on the physical, chemical and morphological characteristics of biofilms formed by the cells of Pseudomonas desmolyticum on granular activated carbon (GAC) in PPBR during biodegradation of phenol. The percentage degradation of phenol decreased from 99% to 73% with an increase in dilution rate from 0.33 h?1 to 0.99 h?1 showing that residence time in the reactor governs the phenol removal efficiency rather than the external mass transfer limitations. Lower dilution rates favor higher production of biomass, extracellular polymeric substances (EPS) as well as the protein, carbohydrate and humic substances content of EPS. Increase in dilution rate leads to decrease in biofilm thickness, biofilm dry density, and attached dry biomass, transforming the biofilm from dense, smooth compact structure to a rough and patchy structure. Thus, the performance of PPBR in terms of dynamic and steady-state biofilm characteristics associated with phenol biodegradation is a strong function of dilution rate. Operation of PPBR at lower dilution rates is recommended for continuous biologic treatment of wastewaters for phenol removal.

关键词： Biofilm     Exopolymeric substances     Phenol     Dilution rate     Pulsed plate bioreactor    

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Performance assessment of Alccofine with silica fume, fly ash and slag for development of high strength mortar

Shivang D. JAYSWAL; Mahesh MUNGULE

《结构与土木工程前沿（英文）》 2022年 第16卷 第5期   页码 576-588 doi: 10.1007/s11709-022-0826-0

摘要： Previous studies on concrete have identified silica fume (SF) as the most effective supplementary material, whereas fly ash (FA) and slag have been identified as economical materials with long term strength potential. Development of blended cement mortar referred to as blended mortar (BM) requires similar assessment. The present study explores the application of Alccofine (AL) as supplementary material and compares its performance with conventional materials namely SF, FA and ground granulated blast furnace slag (GGBS). The mortar specimens with binder to fine-aggregates (b/f ) ratio of 1:2 are prepared at water to binder (w/b) ratios of 0.4 and 0.35. The strength values and stress-strain curve for control and BM specimens are obtained at 7, 28, 56, and 90 d curing periods. The assessment based on strength activity index, k-value method and strength estimation model confirms that AL, despite lower pozzolanic activity, contributes to strength gain, due to reduced dilution effect. Assessment of stress-strain curves suggests that the effect of w/b ratio is more dominant on the elastic modulus of BM specimens than on control specimens. The observations from the study identify enhanced strength gain, improved elastic modulus and higher energy absorption as key contributions of AL making it a potential supplementary material.

关键词： Alccofine     high strength mortar     efficiency factor     dilution effect    

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Measurement of activity coefficients at infinite dilution for hydrocarbons in imidazolium-based ionic

ZHU Jiqin, YU Yanmei, CHEN Jian, FEI Weiyang

《化学科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 190-194 doi: 10.1007/s11705-007-0035-3

摘要： The separations of olefin/paraffin, aromatic/aliphatic hydrocarbons or olefin isomers using ionic liquids instead of volatile solvents have interested many researchers. Activity coefficients γ at infinite dilution of a solute in ionic liquid are generally used in the selection of solvents for extraction or extractive distillation. In fact, the measurement of γ by gas-liquid chromatography is a speedy and cost-saving method. Activity coefficients at infinite dilution of hydrocarbon solutes, such as alkanes, hexenes, alkylbenzenes, styrene, in 1-allyl-3-methylimidazolium tetrafluoroborate ([AMIM][BF]) and 1-butyl-3-methyl imidazolium hexafluorophosphate ([BMIM][PF6]), 1-isobutenyl-3-methylimidazolium tetrafluoroborate ([MPMIM][BF]) and [MPMIM][BF]-AgBF have been determined by gas-liquid chromatography using ionic liquids as stationary phase. The measurements were carried out at different temperatures from 298 to 318 K. The separating effects of these ionic liquids for alkanes/hexane, aliphatic hydrocarbons/benzene and hexene isomers have been discussed. The hydrophobic parameter, dipole element, frontier molecular orbital energy gap and hydration energy of these hydrocarbons were calculated with the PM3 semi-empirical quantum chemistry method. The quantitative relations among the computed structure parameters and activity coefficients at infinite dilution were also developed. The experimental activity coefficient data are consistent with the correlated and predicted results using QSPR models.

关键词： cost-saving     consistent     coefficient     measurement     separating    

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Dilution sampling and analysis of particulate matter in biomass-derived syngas

Xiaoliang WANG, Curtis ROBBINS, S. Kent HOEKMAN, Judith C. CHOW, John G. WATSON, Dennis SCHUETZLE

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 320-330 doi: 10.1007/s11783-011-0347-x

摘要： Thermochemical biomass gasification, followed by conversion of the produced syngas to fuels and electrical power, is a promising energy alternative. Real-world characterization of particulate matter (PM) and other contaminants in the syngas is important to minimize damage and ensure efficient operation of the engines it powers and the fuels created from it. A dilution sampling system is demonstrated to quantify PM in syngas generated from two gasification plants utilizing different biomass feedstocks: a BioMax 15 Biopower System that uses raw and torrefied woodchips as feedstocks, and an integrated biorefinery (IBR) that uses rice hulls and woodchips as feedstocks. PM mass concentrations in syngas from the IBR downstream of the purification system were 12.8–13.7 μg·m , which were significantly lower than the maximum level for catalyst protection (500 μg·m ) and were 2–3 orders of magnitude lower than those in BioMax 15 syngas (2247–4835 μg·m ). Ultrafine particle number concentration and PM chemical constituents were also much lower in the IBR syngas than in the BioMax 15. The dilution sampling system enabled reliable measurements over a wide range of concentrations: the use of high sensitivity instruments allowed measurement at very low concentrations (~1 μg·m ), while the flexibility of dilution minimized sampling problems that are commonly encountered due to high levels of tars in raw syngas (~1 g·m ).

关键词： dilution source sampling     syngas characterization     biomass gasification     ultrafine particles    

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propanediol from glycerol-based fermentations of Klebsiella pneumoniae by alcohol precipitation and dilution

GAO Sujun, SUN Yaqin, XIU Zhilong

《化学科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 202-207 doi: 10.1007/s11705-007-0037-1

摘要： The separation of 1,3-propanediol from the glycerol-based fermentation broth of plays an important role during the microbial production of 1,3-propanediol. In this paper, the separation of 1,3-propanediol from fermentative broth by a combination of ultrafiltration and alcohol dilution crystallization was investigated. The broth was first filtered by ultrafiltration, and 99% of cells, 89.4% of proteins and 69% of nucleic acids were removed. The obtained broth was further condensed by vac uum distillation, and then alcohol was added. The macromolecular impurities, such as nucleic acids, polysaccharides and proteins, were precipitated, and inorganic and organic salts were crystallized. The optimal volume ratio of alcohol added to the condensed fermentation broth was determined to be 2:1. As a result, proteins, nucleic acids and electric conductivity decreased by 97.4%, 89.7% and 95.8%, respectively, compared with the fermentative broth. The influences of pH and water content in condensed broth on alcohol precipitation and dilution crystallization were also investigated. The experimen tal results indicated that alcohol precipitation and dilution crystallization was feasible and effective for the separation of 1,3-propanediol from actual fermentation broth.
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Dilution rate and microstructure of TIG arc Ni-Al powder surfacing layer

SHAN Jiguo, DONG Wei, TAN Wenda, ZHANG Di, REN Jialie

《机械工程前沿（英文）》 2007年 第2卷 第1期   页码 20-24 doi: 10.1007/s11465-007-0003-0

摘要： Surfacing beads are prepared by a direct current tungsten inert gas arc nickel-aluminum (Ni-Al) powder surfacing process. With the aim of controlling the dilution rate and obtaining surfacing beads rich in intermetallic compounds, the effects of surfacing parameters on geometric parameters, dilution rate, composition, and microstructure of the bead are investigated. An assistant cooler, which can potentially reduce the temperature of the base metal, is used in the surfacing process and its effect on dilution rate and microstructure is studied. The result indicates that with the surfacing parameter combination of low current and speed, the width and penetration of the bead decrease, reinforcement increases, and dilution rate drops markedly. With the reduction of the parameter combination, the intergranular phase ?-(Fe, Ni) is formed in the grain boundaries of Ni-Al intermetallic matrix instead of the intergranular phase ?-Fe, and large amount of intermetallics are obtained. With the use of an assistant cooler on a selected operation condition during the surfacing process, the reinforcement of the bead increases, penetration decreases, and dilution rate declines. The use of an assistant cooler helps obtain a surfacing bead composed of only intermetallics.

关键词： decrease     Ni-Al     surfacing parameter     temperature     surfacing process    

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Microbial community structure and dynamics of starch-fed and glucose-fed chemostats during two years of continuous operation

Min GOU,Jing ZENG,Huizhong WANG,Yueqin TANG,Toru SHIGEMATSU,Shigeru MORIMURA,Kenji KIDA

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 368-380 doi: 10.1007/s11783-015-0815-9

摘要： The microbial community structures of two mesophilic anaerobic chemostats, one fed with glucose, the other with starch as sole carbon sources, were studied at various dilution rates (0.05–0.25 d for glucose and 0.025–0.1 d for starch) during two years continuous operation. In the glucose-fed chemostat, the aceticlastic methanogen spp. and hydrogenotrophic methanogen spp. predominated at low dilution rates, whereas spp. and the hydrogenotrophic spp. predominated together when dilution rates were greater than 0.1 d . Bacteria affiliated with the phyla Bacteroidetes, Spirochaetes, and Actinobacteria predominated at dilution rates of 0.05, 0.1, and 0.15 d , respectively, while Firmicutes predominated at higher dilution rates (0.2 and 0.25 d ). In the starch-fed chemostat, the aceticlastic and hydrogenotrophic methanogens coexisted at all dilution rates. Although bacteria belonging to only two phyla were mainly responsible for starch degradation (Spirochaetes at the dilution rate of 0.08 d and Firmicutes at other dilution rates), different bacterial genera were identified at different dilution rates. With the exception of Archaea in the glucose-fed chemostat, the band patterns revealed by denaturing gradient gel electrophoresis (DGGE) of the microbial communities in the two chemostats displayed marked changes during long-term operation at a constant dilution rate. The bacterial community changed with changes in the dilution rate, and was erratic during long-term operation in both glucose-fed and starch-fed chemostats.

关键词： microbial community     glucose degradation     starch degradation     dilution rate     continuous methane fermentation     phylogenetic analysis    

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Analysis of effect of different construction methods of piles on the end effect on skin friction of piles

ZHOU Hongbo, CHEN Zhuchang

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 458-463 doi: 10.1007/s11709-007-0062-7

摘要： Based on the comparative analysis of end effect on skin friction of displacement-pile (driven pile), the end effect on skin friction of bored pile is studied. The end effect on skin friction between driven pile and bored pile is different and the end effect on skin friction of bored pile is reduce of skin friction in the soil layer adjacent to the pile end. The degradation degree of skin friction is deduced with the increase of the distance from pile end. The concept of additional mud cake formed by the effect of cushion at the bottom of borehole during pouring concrete is introduced to explain the mechanism of end effect on skin friction of the bored pile. The test results of post-grouting piles indicate that the post-grouting technique is an effective way to improve the end effect on skin friction of bored pile.

关键词： distance     different     concept     additional     bottom    

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A review on different theoretical models of electrocaloric effect for refrigeration

《能源前沿（英文）》 2023年 第17卷 第4期   页码 478-503 doi: 10.1007/s11708-023-0884-6

摘要： The performance parameters for characterizing the electrocaloric effect are isothermal entropy change and the adiabatic temperature change, respectively. This paper reviews the electrocaloric effect of ferroelectric materials based on different theoretical models. First, it provides four different calculation scales (the first-principle-based effective Hamiltonian, the Landau-Devonshire thermodynamic theory, phase-field simulation, and finite element analysis) to explain the basic theory of calculating the electrocaloric effect. Then, it comprehensively reviews the recent progress of these methods in regulating the electrocaloric effect and the generation mechanism of the electrocaloric effect. Finally, it summarizes and anticipates the exploration of more novel electrocaloric materials based on the framework constructed by the different computational methods.

关键词： electrocaloric effect     effective Hamiltonian     phase-field modeling     different theoretical models    

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A new miniaturized engine based on thermomagnetic effect of magnetic fluids

Lujun ZHOU, Yimin XUAN, Qiang LI, Wenlei LIAN

《能源前沿（英文）》 2009年 第3卷 第2期   页码 160-166 doi: 10.1007/s11708-009-0018-9

摘要： A new engine system, essentially consisting of a permanent NdFeB magnet, a kerosene-based magnetic fluid and a rotor, is proposed based on the thermomagnetic effect of a temperature-sensitive magnetic fluid. The rotor was driven by the thermal convection of the magnetic fluid in the presence of a homogeneous external magnetic field. A digital camera was used to record the rotation speed of the rotor to investigate the performance of the engine system under varying conditions such as heat load, heat sink temperature, and magnetic field distribution. The peak angle velocity obtained for the rotor was about 2.1 rad/min. The results illustrate that the rotation speed of the rotor increases as the input heat load increases, or as the heat sink temperature decreases. The performance of the motor is considerably influenced by the magnetic field imposed. Therefore, the performance of such an engine can be controlled conveniently by changing the external magnetic field and/or the temperature distribution in the fluid.

关键词： magnetic fluid     thermomagnetic effect     engine    

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The cooperation effect of Ni and Pt in the hydrogenation of acetic acid

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 397-407 doi: 10.1007/s11705-021-2076-4

摘要： The catalytic hydrogenation of carboxylic acid to alcohols is one of the important strategies for the conversion of biomass. Herein, a series of Ni-doped PtSn catalysts were prepared, characterized and studied in the hydrogenation of acetic acid. The Ni dopant has a strong interaction with Pt, which promotes the hydrogen adsorption, providing an activated hydrogen-rich environment for the hydrogenation. Meanwhile, the presence of Ni also improves the Pt dispersion, giving more accessible active sites for hydrogen activation. The cooperation of Pt and Ni significantly promotes the catalytic activity of the hydrogenation of acetic acid to ethanol. As a result, the catalyst with 0.1% Ni exhibits the best reaction activity, and its space time yield is twice as that of the PtSn/SiO2 catalyst. It provides a meaningful instruction on the catalyst design for the carboxylic acid hydrogenation.

关键词： acetic acid     ethanol     hydrogenation     Pt     Ni     cooperation effect    

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Direct energy rebound effect for road transportation in China

《工程管理前沿（英文）》   页码 597-611 doi: 10.1007/s42524-023-0276-y

摘要： The enhancement of energy efficiency stands as the principal avenue for attaining energy conservation and emissions reduction objectives within the realm of road transportation. Nevertheless, it is imperative to acknowledge that these objectives may, in part or in entirety, be offset by the phenomenon known as the energy rebound effect (ERE). To quantify the long-term EREs and short-term EREs specific to China’s road transportation, this study employed panel cointegration and panel error correction models, accounting for asymmetric price effects. The findings reveal the following: The long-term EREs observed in road passenger transportation and road freight transportation range from 13% to 25% and 14% to 48%, respectively; in contrast, the short-term EREs in road passenger transportation and road freight transportation span from 36% to 41% and 3.9% to 32%, respectively. It is noteworthy that the EREs associated with road passenger transportation and road freight transportation represent a partial rebound effect, falling short of reaching the magnitude of a counterproductive backfire effect. This leads to the inference that the upsurge in energy consumption within the road transportation sector cannot be solely attributed to advancements in energy efficiency. Instead, various factors, including income levels, the scale of commodity trade, and industrial structure, exert more substantial facilitating influences. Furthermore, the escalation of fuel prices fails to dampen the demand for energy services, whether in the domain of road passenger transportation or road freight transportation. In light of these conclusions, recommendations are proffered for the formulation of energy efficiency policies pertinent to road transportation.

关键词： road transportation     direct energy rebound effect     asymmetric price effects     panel data model    

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Photoaging mechanism of microplastics: a perspective on the effect of dissolved organic matter in natural

《环境科学与工程前沿（英文）》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1743-8

摘要：

● Microplastics (MPs) undergo photoaging in natural water under light irradiation.

关键词： Microplastics     Photoaging     Dissolved organic matter     ROS generation    

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Modeling analysis on solar steam generator employed in multi-effect distillation (MED) system

Zhaorui ZHAO, Bao YANG, Ziwen XING

《能源前沿（英文）》 2019年 第13卷 第1期   页码 193-203 doi: 10.1007/s11708-019-0608-0

摘要： Recently the porous bilayer wood solar collectors have drawn increasing attention because of their potential application in solar desalination. In this paper, a thermodynamic model has been developed to analyze the performance of the wood solar collector. A modeling analysis has also been conducted to assess the performance and operating conditions of the multiple effect desalination (MED) system integrated with the porous wood solar collector. Specifically, the effects of operating parameters, such as the motive steam temperature, seawater flow rate, input solar energy and number of effects on the energy consumption for each ton of distilled water produced have been investigated in the MED desalination system combined with the bilayer wood solar steam generator. It is found that, under a given operating condition, there exists an optimum steam generation temperature of around 145°C in the wood solar collector, so that the specific power consumption in the MED system reaches a minimum value of 24.88 kWh/t. The average temperature difference is significantly affected by the solar heating capacity. With the solar capacity increasing from 50 kW to 230 kW, the average temperature difference increases from 1.88°C to 6.27°C. This parametric simulation study will help the design of efficient bilayer wood solar steam generator as well as the MED desalination system.

关键词： solar energy     steam generating     multi-effect desalination    

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标题 作者 时间 类型 操作

Effect of dilution rate on dynamic and steady-state biofilm characteristics during phenol biodegradation

Veena Bangalore Rangappa, Vidya Shetty Kodialbail, Saidutta Malur Bharthaiyengar

期刊论文

Performance assessment of Alccofine with silica fume, fly ash and slag for development of high strength mortar

Shivang D. JAYSWAL; Mahesh MUNGULE

期刊论文

Measurement of activity coefficients at infinite dilution for hydrocarbons in imidazolium-based ionic

ZHU Jiqin, YU Yanmei, CHEN Jian, FEI Weiyang

期刊论文

Dilution sampling and analysis of particulate matter in biomass-derived syngas

Xiaoliang WANG, Curtis ROBBINS, S. Kent HOEKMAN, Judith C. CHOW, John G. WATSON, Dennis SCHUETZLE

期刊论文

propanediol from glycerol-based fermentations of Klebsiella pneumoniae by alcohol precipitation and dilution

GAO Sujun, SUN Yaqin, XIU Zhilong

期刊论文

Dilution rate and microstructure of TIG arc Ni-Al powder surfacing layer

SHAN Jiguo, DONG Wei, TAN Wenda, ZHANG Di, REN Jialie

期刊论文

Microbial community structure and dynamics of starch-fed and glucose-fed chemostats during two years of continuous operation

Min GOU,Jing ZENG,Huizhong WANG,Yueqin TANG,Toru SHIGEMATSU,Shigeru MORIMURA,Kenji KIDA

期刊论文

李浩然：基于同伴效应与网络效应的“气代煤〞改造决策研究（2020年7月11日）

2022年05月19日

会议视频

Analysis of effect of different construction methods of piles on the end effect on skin friction of piles

ZHOU Hongbo, CHEN Zhuchang

期刊论文

A review on different theoretical models of electrocaloric effect for refrigeration

期刊论文

A new miniaturized engine based on thermomagnetic effect of magnetic fluids

Lujun ZHOU, Yimin XUAN, Qiang LI, Wenlei LIAN

期刊论文

The cooperation effect of Ni and Pt in the hydrogenation of acetic acid

期刊论文

Direct energy rebound effect for road transportation in China

期刊论文

Photoaging mechanism of microplastics: a perspective on the effect of dissolved organic matter in natural

期刊论文

Modeling analysis on solar steam generator employed in multi-effect distillation (MED) system

Zhaorui ZHAO, Bao YANG, Ziwen XING

期刊论文